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Passivation Chemicals, Selection, Use, Trading
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Sodium Nitrite

Chemical Cleaning Use:
For the final passivation of carbon stell surfaces of boilers after acid chemical cleaning.


General:
Synonyms: nitrous acid sodium salt, diazotizing salt, anti-rust
Molecular formula: NaNO2
CAS No: 7632-00-0
EINECS No: 231-555-9

Physical data
Appearance: white to off-white powder
Melting point: 281 C
Density (g cm-3): 2.17
Autoignition temperature: 490 C
Water solubility: soluble

Stability
Stable. Incompatible with reducing agents, strong oxidizing agents, organics and other flammable materials, finely powdered metals. Contact with combustible material may lead to fire. Hygroscopic.


Environmental information
Very toxic to aquatic organisms.

Transport information
UN No 1500. Hazard class 5.1. Packing group III.

Personal protection
Safety glasses, adequate ventilation, gloves.



Hydrogen Peroxide, 30% solution


Chemical Cleaning Use:
(1) For the final passivation of stainless stell surfaces after acid chemical cleaning.

General
Synonyms: albone 30, albone 35, albone 50, albone 70, albone 35cg, albone 50cg, albone 70cg, interox, kastone, perone 30, perone 35, perone 50. Data also applies to solutions of similar strength.

Note: Typical concentrations lie in the range 3%-35%. Solutions of much higher concentration (e.g. 60% and above) present significantly increased risks, and should not be used unless such strength is absolutely essential.
Molecular formula: H2 O2
CAS No: 7722-84-1
EC No: 231-765-0

Physical data
Appearance: colourless liquid
Melting point: ca. -28 C
Boiling point: ca. 114 C
Specific gravity: typically near 1.19
Vapour pressure: 23.3 at 30 C
Flash point:
Explosion limits:
Autoignition temperature:

Stability
Unstable - readily decomposes to water and oxygen. Light sensitive. May develop pressure in the bottle - take care when opening. Forms potentially explosive compounds with ketones, ethers, alcohols, hydrazine, glycerine, aniline, sodium borate, urea, sodium carbonate, triethylamine, sodium fluoride, sodium pyrophosphate and carboxylic acid anhydrides. Materials to avoid include combustibles, strong reducing agents, most common metals, organic materials, metallic salts, alkali, porous materials, especially wood, asbestos, soil, rust, strong oxidizing agents.

Toxicology
Toxic. Corrosive - can causes serious burns. Eye contact can cause serious injury, possibly blindness. Harmful by inhalation, ingestion and skin contact. Typical OEL 1 ppm.


Transport information
UN Major hazard class 5.1. Packing group II. UN No 2014. EMS No 5.1-02.

Personal protection
Safety glasses are essential; acid-resistant gloves are suggested. Suitable ventilation.

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